About this Journal

Online ISSN: 1521-3773    Print ISSN: 1433-7851
Angewandte Chemie
Volume 39, Issue 24, 2000.

© 2000 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany

 

PDF  4391  Cover Picture
Burckhard Seelig, Sonja Keiper, Friedrich Stuhlmann, Andres Jäschke

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4391::AID-ANIE4391>3.0.CO;2-K

 Review
 
PDF  4414-4435  New Applications of Polyfunctional Organometallic Compounds in Organic Synthesis
Andreas Boudier, Lars O. Bromm, Matthias Lotz, Paul Knochel

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4414::AID-ANIE4414>3.0.CO;2-C

PDF  4436-4461  Electron Spin Polarization and Time-Resolved Electron Paramagnetic Resonance: Applications to the Paradigms of Molecular and Supramolecular Photochemistry
Nicholas J. Turro, Mark H. Kleinman, Erdem Karatekin

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4436::AID-ANIE4436>3.0.CO;2-X

 Essay
 
PDF  4463-4468  How Capillary Electrophoresis Sequenced the Human Genome
Norman J. Dovichi, Jianzhong Zhang

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4463::AID-ANIE4463>3.0.CO;2-8

 Highlight
 
PDF  4469-4470  The Pharmaceutical Potential of Manganese-Based Superoxide Dismutase Mimics
Roland Krämer

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4469::AID-ANIE4469>3.0.CO;2-9

 Correspondence
 
PDF  4471-4475  How Can Metallic Ferromagnetism Be Explained? Itinerant Ferromagnetism of the Transition Metals: Our Present Understanding
Gernot Stollhoff

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4471::AID-ANIE4471>3.0.CO;2-I

PDF  4475-4476  Reply
Gregory A. Landrum, Richard Dronskowski

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4475::AID-ANIE4475>3.0.CO;2-V

 Communication
 
PDF  4477-4480  Complete Structural Characterization by Ab Initio X-Ray Powder Diffraction of [{Re(-H)(CO)4}n] and [{Re(-H)(CO)4}6], Inorganic Analogues of Polyethylene and Cyclohexane
Norberto Masciocchi, Giuseppe D'Alfonso, Luca Garavaglia, Angelo Sironi

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4477::AID-ANIE4477>3.0.CO;2-J

PDF  4481-4483  Annelated Heptathiophene: A Fragment of a Carbon-Sulfur Helix
Andrzej Rajca, Hua Wang, Maren Pink, Suchada Rajca

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4481::AID-ANIE4481>3.0.CO;2-G

PDF  4483-4485  Towards the DRED of Resin-Supported Combinatorial Libraries: A Non-Invasive Methodology Based on Bead Self-Encoding and Multispectral Imaging
Hicham Fenniri, Hartmut G. Hedderich, Kenneth S. Haber, Jihane Achkar, Brian Taylor, Dor Ben-Amotz

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4483::AID-ANIE4483>3.0.CO;2-4

PDF  4485-4488  Polymorphism in p-Hydroxybenzoic Acid: The Effect of Intermolecular Hydrogen Bonding in Controlling Proton Order versus Disorder in the Carboxylic Acid Dimer Motif
Benson M. Kariuki, Clare L. Bauer, Kenneth D. M. Harris, Simon J. Teat

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4485::AID-ANIE4485>3.0.CO;2-T

PDF  4488-4491  Structure Determination of an Oligopeptide Directly from Powder Diffraction Data
Emilio Tedesco, Giles W. Turner, Kenneth D. M. Harris, Roy L. Johnston, Benson M. Kariuki

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4488::AID-ANIE4488>3.0.CO;2-B

PDF  4492-4494  Aromatic Aminations by Heterogeneous Ni0/C Catalysis
Bruce H. Lipshutz, Hiroshi Ueda

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4492::AID-ANIE4492>3.0.CO;2-8

PDF  4494-4496  Application of a Spin-Labeled Spin-Trap to the Detection of Nitric Oxide (NO)
Lucien Marx, Andr?Rassat

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4494::AID-ANIE4494>3.0.CO;2-X

PDF  4496-4500  Novel NO Biosensor Based on the Surface Derivatization of GaAs by Hinged Iron porphyrins
Deng Guo Wu, Gonen Ashkenasy, Dmitry Shvarts, Rachel V. Ussyshkin, Ron Naaman, Abraham Shanzer, David Cahen

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4496::AID-ANIE4496>3.0.CO;2-L

PDF  4500-4502  Stereoselective Synthesis of Highly Functionalized C-Glycosides based on Acetal [1,2] and [1,4] Wittig Rearrangements
Katsuhiko Tomooka, Hiroshi Yamamoto, Takeshi Nakai

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4500::AID-ANIE4500>3.0.CO;2-W

PDF  4502-4505  Stereoselective Total Synthesis of Zaragozic Acid A based on an Acetal [1,2] Wittig Rearrangement
Katsuhiko Tomooka, Makoto Kikuchi, Kazunobu Igawa, Masaki Suzuki, Ping-Huai Keong, Takeshi Nakai

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4502::AID-ANIE4502>3.0.CO;2-K

PDF  4505-4508  Subtle Variations in the Long-Range Transmission of Stereochemical Information: Matched and Mismatched Aldol Reactions
Zhicai Wu, Fei Zhang, Samuel J. Danishefsky

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4505::AID-ANIE4505>3.0.CO;2-2

PDF  4509-4511  The Synthesis of CP-263,114 and CP-225,917: Striking Long-Range Stereocontrol in the Fashioning of C7
Qiang Tan, Samuel J. Danishefsky

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4509::AID-ANIE4509>3.0.CO;2-F

PDF  4512-4513  Synthesis and Reactions of Palladium and Platinum Complexes Bearing Diphosphinidenecyclobutene Ligands: A Thermally Stable Catalyst for Ethylene Polymerization
Shintaro Ikeda, Fumie Ohhata, Masaki Miyoshi, Rika Tanaka, Tatsuya Minami, Fumiyuki Ozawa, Masaaki Yoshifuji

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4512::AID-ANIE4512>3.0.CO;2-I

PDF  4513-4515  Highly Selective Ring-Opening/Cross-Metathesis Reactions of Norbornene Derivatives Using Selenocarbene Complexes as Catalysts
Hiroyuki Katayama, Hideto Urushima, Tsuneo Nishioka, Chikaya Wada, Masato Nagao, Fumiyuki Ozawa

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4513::AID-ANIE4513>3.0.CO;2-C

PDF  4516-4518  Crystal Structure of [(Ph(Me)C:N:C(H)Ph)K(tBuOK)2(thf)2]: A Unimetallic Mixed Anion Model for a Superbase?
Philip C. Andrews, Gary D. Fallon, Melissa Maguire, Anna C. Peatt

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4516::AID-ANIE4516>3.0.CO;2-V

PDF  4518-4521  Catalytic Asymmetric Aziridination with Arylborate Catalysts Derived from VAPOL and VANOL Ligands
Jon C. Antilla, William D. Wulff

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4518::AID-ANIE4518>3.0.CO;2-J

PDF  4521-4524  Stereoselective Synthesis of RP- and SP-Dithymidine Phosphorothioates via Chiral Indolooxazaphosphorine Intermediates Derived from Tryptophan
Yixin Lu, George Just

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4521::AID-ANIE4521>3.0.CO;2-M

PDF  4524-4528  Early Transition Metal -Diazoalkane Complexes
Victorio Cadierno, Maria Zablocka, Bruno Donnadieu, Alain Igau, Jean-Pierre Majoral

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4524::AID-ANIE4524>3.0.CO;2-4

PDF  4528-4531  Hybrid Coordination Polymers - Metal Oxide Compounds with Chiral Structures
Li-Min Zheng, Tabatha Whitfield, Xiqu Wang, Allan J. Jacobson

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4528::AID-ANIE4528>3.0.CO;2-H

PDF  4531-4533  [HC{(CMe)(NAr)}2]Al[(NSiMe3)2N2] (Ar=2,6-iPr2C6H3): The First Five-Membered AlN4 Ring System
Chunming Cui, Herbert W. Roesky, Hans-Georg Schmidt, Mathias Noltemeyer

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4531::AID-ANIE4531>3.0.CO;2-K

PDF  4533-4537  Synthesis of Stable Organo(bis-silanetriols): X-Ray Powder Structure of 1,4-Bis(trihydroxysilyl)benzene
Geneviève Cerveau, Robert J. P. Corriu, Bertrand Dabiens, Jean Le Bideau

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4533::AID-ANIE4533>3.0.CO;2-8

PDF  4537-4539  The Essential Role of a ZnII Ion in the Disproportionation of Semiquinone Radical Anion by an Imidazolate-Bridged CuII-ZnII Model of Superoxide Dismutase
Hideki Ohtsu, Shunichi Fukuzumi

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4537::AID-ANIE4537>3.0.CO;2-L

PDF  4539-4542  New Family of Cyclopropanating Reagents: Synthesis, Reactivity, and Stability Studies of Iodomethylzinc Phenoxides
Andr?B. Charette, Sébastien Francoeur, Jonathan Martel, Nicole Wilb

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4539::AID-ANIE4539>3.0.CO;2-9

PDF  4542-4544  A Near-Infrared Luminescent Label Based on YbIII Ions and Its Application in a Fluoroimmunoassay
Martinus H. V. Werts, Richard H. Woudenberg, Peter G. Emmerink, Rob van Gassel, Johannes W. Hofstraat, Jan W. Verhoeven

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4542::AID-ANIE4542>3.0.CO;2-C

PDF  4545-4547  Removal of Benzyl Protecting Groups from Solid-Supported Compounds by Hydrogenolysis Using Palladium Nanoparticles
Osamu Kanie, Gijsbert Grotenbreg, Chi-Huey Wong

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4545::AID-ANIE4545>3.0.CO;2-V

PDF  4547-4551  Tuning the Semiconducting Properties of Sexithiophene by ,-Substitution - ,-Diperfluorohexylsexithiophene: The First n-Type Sexithiophene for Thin-Film Transistors
Antonio Facchetti, Yvonne Deng, Anchuan Wang, Yoshihiro Koide, Henning Sirringhaus, Tobin J. Marks, Richard H. Friend

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4547::AID-ANIE4547>3.0.CO;2-J

PDF  4552-4555  Crystallization of a Large-Pore Three-Dimensional Gallium Fluorophosphate under Mild Conditions
Richard I. Walton, Franck Millange, Thierry Loiseau, Dermot O'Hare, Gérard Férey

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4552::AID-ANIE4552>3.0.CO;2-A

PDF  4555-4557  A One-Dimensional Metallocyclophane with Columnar Aromatic Stacking: The Silver(i) 2-Coordination Complex of 1,2-Benztriphenylene
Megumu Munakata, Gui Ling Ning, Yusaku Suenaga, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Tetsuhiro Ohta

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4555::AID-ANIE4555>3.0.CO;2-T

PDF  4558-4562  Supramolecular Assembly of Hexagonal Mesostructured Germanium Sulfide and Selenide Nanocomposites Incorporating the Biologically Relevant Fe4S4 Cluster
Pantelis N. Trikalitis, Thomas Bakas, Vasilios Papaefthymiou, Mercouri G. Kanatzidis

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4558::AID-ANIE4558>3.0.CO;2-B

PDF  4562-4564  Benzene-Centered Tri- and Tetrametallacarborane Sandwich Complexes
Martin Bluhm, Hans Pritzkow, Walter Siebert, Russell N. Grimes

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4562::AID-ANIE4562>3.0.CO;2-8

PDF  4565-4567  Ground-State Reversal by Matrix Interaction: Electronic States and Vibrational Frequencies of CUO in Solid Argon and Neon
Lester Andrews, Binyong Liang, Jun Li, Bruce E. Bursten

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4565::AID-ANIE4565>3.0.CO;2-R

PDF  4567-4570  Visualization of Single Multivalent Receptor-Ligand Complexes by Transmission Electron Microscopy
Jason E. Gestwicki, Laura E. Strong, Laura L. Kiessling

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4567::AID-ANIE4567>3.0.CO;2-F

PDF  4570-4571  A Remarkable, Stable Radical-Molecule Complex: HO2CF3C(O)OH
Joseph S. Francisco

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4570::AID-ANIE4570>3.0.CO;2-I

PDF  4573-4576  Stochastic Resonance in a Bistable Chemical System: The Oxidation of Ascorbic Acid by Oxygen Catalyzed by Copper(ii) Ions
Peter E. Strizhak, Igor Demjanchyk, Frank Fecher, Friedemann W. Schneider, Arno F. Münster

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4573::AID-ANIE4573>3.0.CO;2-0

PDF  4576-4579  Enantioselective Ribozyme Catalysis of a Bimolecular Cycloaddition Reaction
Burckhard Seelig, Sonja Keiper, Friedrich Stuhlmann, Andres Jäschke

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4576::AID-ANIE4576>3.0.CO;2-J

PDF  4580-4582  (Ph4P)S6 - A Compound Containing the Cyclic Radical Anion S6.-
Bernhard Neumüller, Fritjof Schmock, Reinhard Kirmse, Andreas Voigt, Axel Diefenbach, F. Matthias Bickelhaupt, Kurt Dehnicke

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G

PDF  4582-4586  Conical Intersections in Charge-Transfer Induced Quenching
Adalgisa Sinicropi, Uwe Pischel, Riccardo Basosi, Werner M. Nau, Massimo Olivucci

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4582::AID-ANIE4582>3.0.CO;2-4

PDF  4586-4588  From a Racemate to a Pure Enantiomer by Laser Pulses: Quantum Model Simulations for H2POSH
Yuichi Fujimura, Leticia González, Kunihito Hoki, Dominik Kröner, Jörn Manz, Yukiyoshi Ohtsuki

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4586::AID-ANIE4586>3.0.CO;2-H

PDF  4588-4591  Bis(pentafluorophenyl)xenon, Xe(C6F5)2: A Homoleptic Diorganoxenon Derivative
Nicola Maggiarosa, Dieter Naumann, Wieland Tyrra

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4588::AID-ANIE4588>3.0.CO;2-5

PDF  4591-4593  C6F5XeF, A Key Substrate in Xenon-Carbon Chemistry: Synthesis of Symmetric and Asymmetric Pentafluorophenylxenon(ii) Derivatives
Hermann-Josef Frohn, Michael Theißen

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4591::AID-ANIE4591>3.0.CO;2-8

PDF  4593-4596  An Enantiospecific Synthesis of the Potent Immunosuppressant FR901483
Goetz Scheffler, Hirofumi Seike, Erik J. Sorensen

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4593::AID-ANIE4593>3.0.CO;2-X

PDF  4596-4599  Total Synthesis of (-)-Spirotryprostatin B and Three Stereoisomers
Larry E. Overman, Mark D. Rosen

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4596::AID-ANIE4596>3.0.CO;2-F

PDF  4599-4602  Reconstitution of Channel Proteins in (Polymerized) ABA Triblock Copolymer Membranes
Wolfgang Meier, Corinne Nardin, Mathias Winterhalter

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4599::AID-ANIE4599>3.0.CO;2-Y

PDF  4602-4604  Direct Observation of the Lower Critical Solution Temperature of Surface-Attached Thermo-Responsive Hydrogels by Surface Plasmon Resonance
Erik Wischerhoff, Thomas Zacher, Andr?Laschewsky, El Djouhar Reka?br>
Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4602::AID-ANIE4602>3.0.CO;2-E

PDF  4605-4607  Asymmetric Synthesis of -Substituted -Nitrophosphonic Acids by Phospha-Analogous Michael Addition to Aromatic Nitroalkenes
Dieter Enders, Livio Tedeschi, Jan Willem Bats

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4605::AID-ANIE4605>3.0.CO;2-X

PDF  4607-4609  Breakdown of Bond Length-Bond Strength Correlation: A Case Study
Martin Kaupp, Bernhard Metz, Hermann Stoll

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4607::AID-ANIE4607>3.0.CO;2-L

PDF  4610-4612  Transition Metal Catalyzed Preparation of Grignard Compounds
Borislav Bogdanovi, Manfred Schwickardi

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4610::AID-ANIE4610>3.0.CO;2-O

PDF  4612-4615  Total Synthesis of Lankacyclinol
David R. Williams, Guillermo S. Cortez, Stéphane L. Bogen, Christian M. Rojas

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4612::AID-ANIE4612>3.0.CO;2-C

PDF  4615-4617  Phenylaziridine as a Masked 1,3 Dipole in Reactions with Nonactivated Alkenes
Ioana Ungureanu, Philippe Klotz, Andr?Mann

Published Online: 15 Dec 2000
DOI10.1002/1521-3773(20001215)39:24<4615::AID-ANIE4615>3.0.CO;2-V



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